Electrochemical studies of decamethylferrocene in supercritical carbon dioxide mixtures.

Steady-state macroscale voltammetry in a supercritical carbon dioxide medium.

The electrochemical oxidation and reduction of decamethylferrocene is demonstrated in supercritical carbon dioxide at a macro gold disc electrode at 100 bar and 313 K. Fast mass transport effects were exhibited and the corresponding steady-state voltammetry was observed at high scan rates. A highly lipophilic room temperature ionic liquid that readily dissolved in supercritical CO(2) with aceto...

Measurement and Correlation of Ibuprofen in Supercritical Carbon Dioxide Using Stryjek and Vera EOS

Vetiver Oil Extraction Optimization Using Supercritical Carbon Dioxide Fluid

Solubility Prediction of Drugs in Supercritical Carbon Dioxide Using Artificial Neural Network

The descriptors computed by HyperChem® software were employed to represent the solubility of 40 drug molecules in supercritical carbon dioxide using an artificial neural network with the architecture of 15-4-1. The accuracy of the proposed method was evaluated by computing average of absolute error (AE) of calculated and experimental logarithm of solubilities. The AE (±SD) of data sets was 0.4 ...

Electrochemistry in supercritical fluids: A mini review

a r t i c l e i n f o A brief overview of the literature relating to electrochemical studies and processes undertaken in supercritical fluids is presented. This review mostly concerns carbon dioxide and hydrofluorocarbons, given the accessibility of their supercritical states, and does not consider the emerging body of research in expanded phase electrochemistry.